
柯卓锋(Zhuofeng Ke),男,1980年10月生,籍贯广东,理学博士。中山大学"百人计划"引进人才,教授,博士生导师。
- 中文名称 柯卓锋
- 外文名称 Zhuofeng Ke
- 民族 中国
- 出生日期 1980年10月
工作经历
2019 - 至今中山大学,材来自料科学与工程学院,教授/博导
360百科 2016-2018 中山大学,材料科学与工程学院,副教授/博导
2012-2016 中山大学,化学院督额余能向例江,副教授/博导
2009-2012 日本京都大学,福井谦一FIFC研究员
教育经历
2005-2009 孩给掌旧中山大学/美国北德克萨斯药跟福且科西大学,物理化学,联合培养博士
2002-2005 中山大学,高分子化学与物理,硕士
百别选温还胡1998-2002 中站肥杨致假客速太去序山大学,化学系,本科
荣誉与奖励
广东省自然科学杰出来自青年(2015)
广东特支计划百千万工程青360百科年拔尖人才(2014)
福井谦一FIFC Fellow(2009-2012)
科研方向
1. 可再生能源、可皮握式再生资源与材料
2. 可再生催化与合成新方法
3. 理论属银读互如但病洋计算精准催化剂设计
底代表论文
1. Zhang持, M., Zhang, M.-T., Hou, C., Ke, Zhuo-Feng*, Lu T.-B.* Homogeneous Electrocatalytic Water Oxid但色离盾沿挥听低命吧顶ation at Neutral pH by a Robust Macrocyclic Nickel(II) Complex. An低消架职gew. Chem., Int. 试置味武岩核同要故Ed. DOI: 10.1002/anie.201406983 (2014).
2. Hou, C., Jiang J., Zhang S., Wang G., Zhang Z., Ke, Zhuofeng*, Zhao C.* Hydrogenation of Carbon Dioxide Using Half-Sandwich Cobalt, Rhodium, and Iridium Complexes: DFT Study on the Mechanis今茶么做m and Metal Effect. ACS Catal. 4, 2990–2997 (里牛村进斤级思2014).
3. Zhou院, Y.G., Zha村边单绝前列导杨核ng, X.P., Liang H.Y., Cao Z.K., Zh巴陈书场台庆转菜温岁ao X.Y., He Y.W., Wang S.L., Pang J.Y., Zhou Z.Y., K五南我齐物调包e, Zhuofeng*, Qiu L.Q.* Enantioselective Synthesis of Axially Chiral Biar哪yl Monophosphine Oxides via Direct Asymmetric Suzuki Coupling and 果DFT Investigations of the Enantioselectivity. ACS Catal. 4, 1390–1397 (座叫余一棉半该劳斯开2014).
4. Pet格压来两深停rovaa, G.P., Ke, Zhuofeng, Park S., Sugiy专取统ama H., Morokum K.* The origin of enantioselectivity for intramolecular Friedel–Crafts reaction catalyzed by supramolecular Cu/DNA catalyst complex. Chem. Phys. Lett. 600, 87-95 (2014).
5. Zhang, X., Ke, Zhuofeng, DeYonker N. J., Xu, H., Li Z.-F., Xu X., Zhang X., Su C.-Y., Phillips D. L., Zhao C.* Mechanism and Enantioselectivity of Dirhodium-Catalyzed Intramolecular C–H Amination of Sulfamate. J. Org. Chem. 78 (24), 12460–12468 (2013).
6. Liu, Y., Ma, L., Chen, W.-H.*, Park, H., Ke, Zhuofeng*, Wang, B*. Binding Mechanism and Synergetic Effects of Xanthone Derivatives as Noncompetitive α-Glucosidase Inhibitors: A Theoretical and Experimental Study. J. Phys. Chem. B 117 (43), 13464 -13471 (2013).
7. Ye, R.-R., Ke, Zhuo-Feng, Tan, C.-P., He, L., Ji, L.-N. & Mao, Z.-W. Histone-Deacetylase-Targeted Fluorescent Ruthenium(II) Polypyridyl Complexes as Potent Anticancer Agents. Chem. Eur. J. 19 (31), 10160 – 10169 (2013).
8. Xu, H. Y., Zhang, X. T., Ke, Zhuofeng, Li, Z. F., Xu, X. Y., Su, C. Y., Phillips, D. L. & Zhao, C. Y. Density functional theory study of the mechanism of zinc carbenoid promoted cyclopropanation of allenamides. Rsc Advances 3, 17131-17142 (2013).
9. Ke, Zhuofeng, Abe, S., Ueno, T., & Morokuma, Keiji. Catalytic Mechanism in Artificial Metalloenzyme: QM/MM Study of Phenylacetylene Polymerization by Rhodium Complex Encapsulated in apo-Ferritin.J. Am. Chem. Soc. 134 (37), 15418–15429 (2012).
10. Ke, Zhuofeng, Abe, S., Ueno, T., & Morokuma, Keiji. Rh-catalyzed Polymerization of Phenylacetylene: Theoretical Studies of the Reaction Mechanism, Regioselectivity and Stereoregularity. J. Am. Chem. Soc. 133 (20), 7926-7941 (2011). (JACS beta Select issue 13)
11. Liu, Y., Ke, Zhuofeng, Liu, Shuwen, Chen, Wen-Hua, Jiang, Shibo; Jiang, Zhi-Hong. "An Amphiphilic Conjugate Approach toward the Design and Synthesis of Betulinic Acid-Polyphenol Conjugates as Inhibitors of the HIV-1 gp41 Fusion Core Formation ". ChemMedChem 6 (9), 1654- 1664 (2011).
12. Gao, H., Ke, Zhuofeng, DeYonker N.J., Wang J., Xu H., Mao Z.-W., Phillips, D.L., Zhao C., Dinuclear Zn(II) Complex Catalyzed Phosphodiester Cleavage Proceeds via a Concerted Mechanism: A Density Functional Theory Study.J. Am. Chem. Soc. 133 (9), 2904–2915 (2011).
13. Ke, Zhuofeng & Cundari, T.R., Palladium-Catalyzed C-H Activation/C-N Bond Formation Reactions: DFT Study of Reaction Mechanisms and Reactive Intermediates. Organometallics 29 (4), 821-834 (2010). (Top10 Most Accessed Articles of Organometallics in 2010)
14. Lee, J.P., Ke, Zhuofeng, Ramirez, M.A., Gunnoe, T.B., Cundari, T.R., Boyle, P.D., & Petersen, J.L., Six-, Five-, and Four-Coordinate Ruthenium(II) Hydride Complexes Supported by N-Heterocyclic Carbene Ligands: Synthesis, Characterization, Fundamental Reactivity, and Catalytic Hydrogenation of Olefins, Aldehydes, and Ketones. Organometallics 28 (6), 1758-1775 (2009).
15. Guo, Z., Xue, J.D., Ke, Zhuofeng, Phillips, D.L., & Zhao, C.Y., Influence of Water Hydrogen Bonding on the Reactions of Arylnitrenium Ions With Guanosine: Hydrogen-Bonding Effects Can Favor Reaction at the C8 Site.J. Phys. Chem. B 113 (18), 6528-6532 (2009).
16. Foley, N.A., Lee, J.P., Ke, Zhuofeng, Gunnoe, T.B., & Cundari, T.R., Ru(II) Catalysts Supported by Hydridotris(pyrazolyl)borate for the Hydroarylation of Olefins: Reaction Scope, Mechanistic Studies, and Guides for the Development of Improved Catalysts. Acc. Chem. Res. 42 (5), 585-597 (2009).
17. Liu, Y., Ke, Zhuofeng, Cui, J.F., Chen, W.H., Ma, L., & Wang, B., Synthesis, inhibitory activities, and QSAR study of xanthone derivatives as alpha-glucosidase inhibitors. Bioorg. Med. Chem. 16 (15), 7185-7192 (2008).
18. Guo, Z., Ke, Zhuofeng, Phillips, D.L., & Zhao, C.Y., Intrinsic reaction coordinate analysis of the activation of CH4 by molybdenum atoms: A density functional theory study of the crossing seams of the potential energy surfaces.Organometallics 27 (2), 181-188 (2008).
19. Foley, N.A., Ke, Zhuofeng, Gunnoe, T.B., Cundari, T.R., & Petersen, J.L., Aromatic C-H activation and catalytic hydrophenylation of ethylene by TpRu{P(OCH2)(3)CEt}(NCMe)Ph. Organometallics 27 (13), 3007-3017 (2008).
20. Lin, X.F., Zhao, C.Y., Che, C.M., Ke, Zhuofeng, & Phillips, D.L., A DFT study on the mechanism of Rh-2(II,II)-catalyzed intramolecular amidation of carbamates. Chem. Asian J. 2 (9), 1101-1108 (2007).
21. Ke, Zhuofeng, Zhou, Y.B., Gao, H., Zhao, C.Y., & Phillips, D.L., On the mechanism and stereochemistry of chiral lithium-carbenoid-promoted cyclopropanation reactions. Chem. Eur. J. 13 (23), 6724-6731 (2007).
22. Ke, Zhuofeng, Zhao, C.Y., & Phillips, D.L., Methylene transfer or carbometalation? A theoretical study to determine the mechanism of lithium carbenoid-promoted cyclopropanation reactions in aggregation and solvation states. J. Org. Chem. 72 (3), 848-860 (2007).
23. Gao, H.Y., Ke, Zhuofeng, Pei, L.X., Song, K.M., & Wu, Q., Drastic ligand electronic effect on anilido-imino nickel catalysts toward ethylene polymerization. Polymer 48 (25), 7249-7254 (2007).
24. Fang, R., Ke, Zhuofeng, Shen, Y., Zhao, C.Y., & Phillips, D.L., Concurrent cyclopropanation by carbenes and carbanions? A density functional theory study on the reaction pathways. J. Org. Chem. 72 (14), 5139-5145 (2007).
25. Zhou, Y.B., Ke, Zhuofeng, & Zhao, C.Y., A theoretical study on the mechanism of ruthenium(II)-catalyzed reaction of organic azide with alkyne. Acta Chim. Sin. 64 (20), 2071-2078 (2006).
26. Zhang, J.K., Ke, Zhuofeng, Bao, F., Long, J.M., Gao, H.Y., Zhu, F.M., & Wu, Q., Ethylene polymerization and oligomerization catalyzed by bulky beta-diketiminato Ni(II) and beta-diimine Ni(II) complexes/methylaluminoxane systems. J. Mol. Catal. A: Chem 249 (1-2), 31-39 (2006).
27. Ye, G.D., Ke, Zhuofeng, Yan, J.W., Zhao, T.Y., Zeng, Z.H., & Chen, Y.L., Low VOC bifunctional photoinitiator based on alpha-hydroxyalkylphenone structure. Polymer 47 (13), 4603-4612 (2006).
28. Li, Z.H., Ke, Zhuofeng, Zhao, C.Y., Geng, Z.Y., Wang, Y.C., & Phillips, D.L., A density functional theory study of aluminum carbenoid (CH3)(2)AlCH2X (X = Cl, Br, I) promoted cyclopropanation reactions compared to IMCH2I (M = Li, Sm, Zn) carbenoids. Organometallics 25 (15), 3735-3742 (2006).
29. Zhang, J.K., Gao, H.Y., Ke, Zhuofeng, Bao, F., Zhu, F.M., & Wu, Q., Investigation of 1-hexene isomerization and oligomerization catalyzed with beta-diketiminato Ni(II) bromide complexes/methylaluminoxane system. J. Mol. Catal. A: Chem 231 (1-2), 27-34 (2005).
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